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Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO)
- Abstract A N‐heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl‐substituted alkenes in which the central carbon–carbon double bond is in a twisted geometry.
| Author: | Debdeep Mandal, Shubhadeep Chandra, Nicolás I. Neuman, Alok Mahata, Arighna Sarkar, Abhinanda Kundu, Srinivas Anga, Hemant Rawat, Carola SchulzkeORCiD, Kaustubh R. Mote, Biprajit Sarkar, Vadapalli Chandrasekhar, Anukul Jana |
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| URN: | urn:nbn:de:gbv:9-opus-40928 |
| DOI: | https://doi.org/10.1002/chem.202000276 |
| Parent Title (English): | Chemistry – A European Journal |
| Publisher: | Wiley |
| Place of publication: | Hoboken, New Jersey |
| Document Type: | Article |
| Language: | English |
| Date of first Publication: | 2020/05/12 |
| Release Date: | 2020/12/08 |
| Tag: | C-F activation; N-heterocyclic olefins; alkenes; fluorine; nucleophilic substitution |
| GND Keyword: | - |
| Volume: | 26 |
| Issue: | 27 |
| First Page: | 5951 |
| Last Page: | 5955 |
| Faculties: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Biochemie |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung |