Bitte verwenden Sie diesen Link, wenn Sie dieses Dokument zitieren oder verlinken wollen: https://nbn-resolving.org/urn:nbn:de:gbv:9-opus-108050
Fine-Tuning Redox Properties of Heteroleptic Molybdenum Complexes through Ligand-Ligand-Cooperativity
- Heteroleptic molybdenum complexes bearing 1,5-diaza-3,7-diphosphacyclooctane (P2N2) and non-innocent dithiolene ligands were synthesized and electrochemically characterized. The reduction potentials of the complexes were found to be fine-tuned by a synergistic effect identified by DFT calculations as ligand-ligand cooperativity via non-covalent interactions. This finding is supported by electrochemical studies combined with UV/Vis spectroscopy and temperature-dependent NMR spectroscopy. The observed behavior is reminiscent of enzymatic redox modulation using second ligand sphere effects.
Download full text files
Additional Services
Statistics
| Author: | Benedict J. Elvers, Sebastian Pätsch, Siva S. M. Bandaru, Vera Krewald, Carola Schulzke, Christian Fischer |
|---|---|
| URN: | urn:nbn:de:gbv:9-opus-108050 |
| DOI: | https://doi.org/10.1002/anie.202303151 |
| ISSN: | 1521-3773 |
| Parent Title (English): | Angewandte Chemie International Edition |
| Publisher: | Wiley |
| Place of publication: | Hoboken, NJ |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2023/04/14 |
| Date of first Publication: | 2023/06/19 |
| Release Date: | 2024/03/04 |
| Tag: | Ligand-Ligand Cooperativity; Non-Innocence Ligands; Noncovalent Interactions; Redox Chemistry |
| Volume: | 62 |
| Issue: | 25 |
| Article Number: | e202303151 |
| Page Number: | 5 |
| Faculties: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Biochemie |
| Collections: | weitere DFG-förderfähige Artikel |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 4.0 International |